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11.
H. Hora 《Czechoslovak Journal of Physics》2003,53(3):199-217
The anomaly of ion emission at laser irradiation of targets measured by Badziak et al. was analyzed on the background of the extensive research in the past. In contrast to the irradiation with lasers of longer than 100 ps pulse duration, a drastic decrease of the maximum ion energies was measured with ps pulses. Very strange was the observation that the number of emitted fast ions was intensity independent. The usual ponderomotive or relativistic self-focusing theory and related processes could not explain the results. Instead a direct interaction within the skin depth of the irradiated target was concluded. This model confirms the plane geometry nonlinear force interaction in the ps range producing fast plasma blocks moving perpendicular off or into the target. The block moving into the target opens a new scheme of laser fusion by modifying the experiments of Norreys et al. The use of relatively low subrelativistic laser intensities for the new scheme of laser fusion is evaluated on the background of the long years studies of nonlinear force driven plasma blocks and earlier interpenetration fusion reactions for providing the parameters for expected fusion gains much higher than the experiment of Norreys et al. for a fusion power scheme. 相似文献
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15.
O-Glycosylations using thiomethyl glycosides as donors were compared under both frozen and unfrozen conditions. In the presence of MeOTf as a promoter, enormous rate acceleration was observed when the glycosylation was conducted in p-xylene below its freezing point. 相似文献
16.
Conducting drop tests to investigate impact behavior and identify failure mechanisms of small-size electronic products is
generally expensive and time-consuming. Nevertheless, strict drop/impact performance criteria for hand-held electronic products
such as cellular phones play a decisive role in the design because they must withstand unexpected shocks. The design of product
durability on impact has heavily relied on the designer's intuition and experience. In this study, a reliable drop/impact
simulation for a cellular phone is carried out using the explicit code LS-DYNA. Subsequently globallocal experimental verification
is accomplished by means of high-speed photography and impact response measurement. Using this methodology, we predict potential
damage locations in a cellular phone and compare them with real statistical data. It is envisaged that development of a reliable
methodology of drop/impact simulation will provide us with a powerful and efficient vehicle for improvement of the design
quality and reduction of the product development cycle. 相似文献
17.
Poly(ortho‐phenylene ethynylene)s (PoPEs) have been synthesized via an in situ activation/coupling AB′ polycondensation protocol. The resulting polymers have been characterized by several analytical methods and are shown to have no structural defects. Although the Sonogashira–Hagihara polycondensation reaction is less efficient than for the preparation of the corresponding meta‐ and para‐linked polymers, presumably because of steric hindrance caused by the ortho substituents, the process can be accelerated by the use of microwave irradiation. Optical spectroscopy indicates solvent‐dependent conformational changes between extended transoid and helical cisoid conformations, providing the first experimental evidence for solvophobically driven folding of the PoPE backbone. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1619–1627, 2006 相似文献
18.
A model is considered in which the bonds of a lattice are covered by rodlike molecules. Neighboring molecular ends interact with orientation-dependent interactions. The model exhibits closed -loop phase diagrams and double critical points. Exact coexistence surfaces are calculated for the model on the Bethe, honeycomb, and square lattices. The nature of the doubling of the critical exponent near a double critical point is calculated. The behavior of the critical line in the neighborhood of a double critical point is calculated exactly. 相似文献
19.
R. T. Olsson H. E. Bair V. Kuck A. Hale 《Journal of Thermal Analysis and Calorimetry》2004,76(2):367-377
Thin films of 3,4-epoxycyclohexylmethyl 3',4'-epoxycyclohexane carboxylate were UV irradiated (1.1 J cm-2) under isothermal conditions ranging from 0 to 50°C. Under these conditions the polymerization advanced quickly but only
to a conversion level of less than 10% before the reaction rate slowed by more than an order of magnitude. This drop off in
rate was not caused by the glass transition temperature, T
g, reaching or exceeding the reaction temperature, T
rxn, since the epoxide's T
g remained at least 40°C below T
rxn. Raising the sample temperature above 60°C caused a sharp increase in the conversion level. At 100°C conversion exceeds 80%
and the ultimate T
g approaches 190°C. The addition of 10 mass% 1,6-hexanediol, HD, to the epoxy caused the conversion at room temperature to
quintuple over the level obtained without the alcohol present. The heat liberated from this alcohol epoxy blend during cure
on a UV conveyor belt system caused the sample's temperature to increase by about 100°C above ambient whereas the epoxy alone
under these conditions only experienced a modest temperature rise of about 26°C. If the amount of HD in the blend is increased
above 10% the heat of reaction at 23°C decreases due to HD being trapped in a nonreactive crystalline phase. Boosting reaction
temperatures above 50°C melts the HD crystals and yields significantly improved conversion ratios. As the level of alcohol
blended with the epoxy is raised its ultimate T
g is lowered and when the concentration of alcohol in the blend nears 30 mass%T
g drops below room temperature.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
20.
The distribution of the likelihood ratio for mixtures of densities from the one-parameter exponential family 总被引:2,自引:0,他引:2
Dankmar Böhning Ekkehart Dietz Rainer Schaub Peter Schlattmann Bruce G. Lindsay 《Annals of the Institute of Statistical Mathematics》1994,46(2):373-388
We here consider testing the hypothesis ofhomogeneity against the alternative of a two-component mixture of densities. The paper focuses on the asymptotic null distribution of 2 log
n
, where
n
is the likelihood ratio statistic. The main result, obtained by simulation, is that its limiting distribution appears pivotal (in the sense of constant percentiles over the unknown parameter), but model specific (differs if the model is changed from Poisson to normal, say), and is not at all well approximated by the conventional
(2)
2
-distribution obtained by counting parameters. In Section 3, the binomial with sample size parameter 2 is considered. Via a simple geometric characterization the case for which the likelihood ratio is 1 can easily be identified and the corresponding probability is found. Closed form expressions for the likelihood ratio
n
are possible and the asymptotic distribution of 2 log
n
is shown to be the mixture giving equal weights to the one point distribution with all its mass equal to zero and the 2-distribution with 1 degree of freedom. A similar result is reached in Section 4 for the Poisson with a small parameter value (0.1), although the geometric characterization is different. In Section 5 we consider the Poisson case in full generality. There is still a positive asymptotic probability that the likelihood ratio is 1. The upper precentiles of the null distribution of 2 log
n
are found by simulation for various populations and shown to be nearly independent of the population parameter, and approximately equal to the (1–2)100 percentiles of
(1)
2
. In Sections 6 and 7, we close with a study of two continuous densities, theexponential and thenormal with known variance. In these models the asymptotic distribution of 2 log
n
is pivotal. Selected (1–) 100 percentiles are presented and shown to differ between the two models. 相似文献